|
|
glycyrrhizin + H2O <=> D-glucuronyl_beta-1,2-D-glucuronic_acid + glycyrrhetinic_acid
|
3.2.1.128
glycyrrhizin hydrolase
|
–
|
|
| |
BRENDA:
BR48192
KEGG:
R03906
|
|
|
|
11-oxo-beta-amyrin + 3 O2 + 3 reduced_flavodoxin <=> glycyrrhetinic_acid + 3 flavin + 4 H2O
|
1.14.14.115
11-oxo-beta-amyrin 30-oxidase
|
–
|
|
| |
BRENDA:
BR50517
KEGG:
R10316
|
|
|
|
glycyrrhetaldehyde + O2 + reduced_flavodoxin <=> glycyrrhetinic_acid + flavin + H2O
|
1.14.14.115
11-oxo-beta-amyrin 30-oxidase
|
–
|
|
| |
BRENDA:
BR50520
KEGG:
R10315
|
|
|
|
H2O + glycyrrhizin <=> glycyrrhetinic_acid + 1,2-beta-D-glucosyluronate-D-glucuronate
|
3.2.1.128
glycyrrhizin hydrolase
|
–
|
|
| |
MetaCyc:
GLYCYRRHIZINATE-BETA-GLUCURONIDASE-RXN
|
|
|
|
glycyrrhetinic_acid + NADP+ <=> 3,11-dioxoolean-12-en-30-oic_acid + NADPH + H+
|
1.1.1.393
3beta-hydroxycholanate 3-dehydrogenase (NADP+)
|
–
|
|
| |
MetaCyc:
RXN-12687
|
|
|
|
glycyrrhetaldehyde + reduced_[NADPH-hemoprotein_reductase] + O2 <=> glycyrrhetinic_acid + oxidized_[NADPH-hemoprotein_reductase] + H2O + H+
|
not assigned
|
–
|
M
|
| |
MetaCyc:
RXN-13494
|
|
|
|
11-deoxoglycyrrhetinic_acid <=> glycyrrhetinic_acid
|
not assigned
|
–
|
M
|
| |
MetaCyc:
RXN-13496
|
|
|
|
11-oxo-beta-amyrin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> glycyrrhetinic_acid + oxidized_[NADPH-hemoprotein_reductase] + H2O + H+
|
1.14.14.115
11-oxo-beta-amyrin 30-oxidase
|
–
|
|
| |
MetaCyc:
RXN-13506
|
|
|
|
glycyrrhetinic_acid + UDP-glucuronate <=> UDP + glycyrrhetinic_acid-3-O-glucuronide
|
2.4.1.17
glucuronosyltransferase
|
–
|
|
| |
BRENDA:
BS455746
|
|
|
|
glycyrrhizin + H2O <=> glycyrrhetinic_acid + 2 D-glucuronate
|
3.2.1.139
alpha-glucuronidase
|
–
|
|
| |
BRENDA:
BS13765
|
|
|
|
UDP-glucose + glycyrrhetinic_acid <=> UDP + glycyrrhetinic_acid_3-O-beta-monoglucose
|
2.4.1.368
oleanolate 3-O-glucosyltransferase
|
–
|
|
| |
BRENDA:
BS448224
|
|
